Diethyl sulfide

Diethyl sulfide
Identifiers
CAS number 352-93-2 Y
PubChem 6163
ChemSpider 9233 Y
EC number 206-526-9
KEGG C14706 Y
ChEBI CHEBI:27710 Y
ChEMBL CHEMBL117181 Y
RTECS number LC7200000
Jmol-3D images Image 1
Properties
Molecular formula C4H10S
Molar mass 90.19
Appearance Clear liquid
Density 0.837 g/cm3
Melting point

-103.8 °C, 169 K, -155 °F

Boiling point

92 °C, 365 K, 198 °F

Solubility in water insoluble
Solubility in ethanol fully miscible
Solubility in diethyl ether fully miscible
Refractive index (nD) 1.44233
Hazards
MSDS External MSDS
R-phrases R11 R65
S-phrases (S2) S9 S16 S51 S62
Main hazards Skin and eye irritant. Highly flammable liquid and vapor
NFPA 704
3
2
1
Flash point −10 °C
Related compounds
Related thioethers dimethyl sulfide
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Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)
Infobox references

Diethyl sulfide is a clear flammable chemical compound with a pungent garlic-like odor. It has the chemical formula C4H10S, though it can also be written (C2H5)2S or Et2S to make its chemical structure more clear. It is prepared by treating ethanol with concentrated sulfuric acid, partially neutralizing the new solution with sodium carbonate, then distilling the resulting sodium ethyl sulfate in a solution containing potassium sulfide.[1]

Diethyl sulfide is used as a solvent for anhydrous minerals and in plating baths for gold and silver.[1]

References

  1. ^ a b Merck index of Chemicals and Drugs, 9th ed., monograph 3801